Homo- and Copolymerizations of Ethylene and Norbornene Using Bis(β-ketoamino) Titanium Catalysts Containing Pyrazolone Rings

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Homo- and Copolymerizations of Ethylene and Norbornene Using Bis(-ketoamino) Titanium Catalysts Containing Pyrazolone Rings

A series of bis(β-ketoamino) titanium complexes containing pyrazolone rings (1–3) have been synthesized, characterized, and used as precursors for homoand copolymerization of ethylene and norbornene. The titanium complexes activated with methylaluminoxane (MAO) exhibited good activities for homopolymerization of ethylene (E) to produce linear polyethylenes (PEs). Ethylene–norbornene copolymers ...

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A series of anilido–imine chromium complexes have been used as precursors to catalyze homoand copolymerization of ethylene and norbornene. The chromium complexes activated with methylalumoxane (MAO) exhibit good activities for homopolymerization of ethylene (E) to produce linear polyethylene and moderate activities for norbornene (N) polymerization to afford vinyl-type polynorbornene. Ethylene–...

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ژورنال

عنوان ژورنال: Polymers

سال: 2017

ISSN: 2073-4360

DOI: 10.3390/polym9070262